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Exploring The Power of Catalysis for New Reaction Development
Independent Publications
Publications
2024
26. Photoinduced Ni-Catalyzed Carbohalogenation of gem-Difluoro and Trifluoromethyl Tethered Alkenes.
Manuscript under preparation
25. Pd-Catalyzed Enantioselective Reductive Heck Reaction of mono-Fluoro, gem-Difluoro, and CF3 tethered-Alkenes.
Manuscript under preparation
24. gem-Difluoroallene (DFA): An Emerging Versatile Synthetic Precursor to Enable Diverse Fluorinated Molecules.
Kota Sathish, Swati Jain, Naveen Sihag, and M Ramu Yadav*
Org. Biomol. Chem. 2024, 22, 8078-8096
(Invited article: Celebrating the 100th birthday of Professor Sukh Dev)
23. Pd-Catalyzed Cascade Heck/C(sp3)-H Activation for Spirocyclopropyl Oxindoles.
Saleem Hafeez†, Ruchi Sharma†, Swati Jain†, Naveen Sihag, Hemaang Bhartiya, Jitendra Singh, S. Rajagopala Reddy* and M Ramu Yadav*
Org. Lett. 2024, 26, 5069-5073
22. Pd-Catalyzed Double Heck and Heck-Suzuki Cascade-Reaction of N-(o-Bromoaryl) CF3-Acrylamides.
Ruchi Sharma, Naveen Sihag, Hemaang Bhartiya, Shivangi Saini, Ashish Kumar and M Ramu Yadav*
Org. Chem. Front. 2024, 11, 1736-1741
21. Harnessing Photocatalytic and Electrochemical Approaches for C-H Bond Trifluoromethylation and Fluoroalkylation.
Ranjay Shaw†, Naveen Sihag†, Hemaang Bhartiya† and M. Ramu Yadav*
Org. Chem. Front. 2024, 11, 954-1014
2023
20. Ligand-free Pd-catalyzed double Heck reaction of N-(o-bromoaryl)acrylamides with α-F/CF3-acrylates.
Ruchi Sharma, Swati Jain†, Naveen Sihag†, M Ramu Yadav*
Chem. Commun. 2023, 59, 8945-8948
19. Cu(I)/N,N-Imine Ligand Catalyzed C(sp3)–C(sp) Coupling of Alkyl Bromides with Alkynes: Scope and Mechanistic Investigation.
Swati Jain, Anmol, Ruchi Sharma, Tarak Karmakar and M. Ramu Yadav*
Org. Lett. 2023, 25, 5437–5442
18. Photoinduced Alkyl/Aryl Radical Cascade for the Synthesis of Quaternary CF3-Containing Oxindoles and Indoline Alkaloids.
Ranjay Shaw†; Naveen Sihag†; Swati Jain; Ruchi Sharma; M. Ramu Yadav*
J. Org. Chem. 2023, 88, 5652–5660
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2022
17. Cu(II)-Catalyzed Unsymmetrical Dioxidation of gem-Difluoroalkenes to Generate α,α-Difluorinated-α-phenoxyketones.
Suvajit Koley; Kaylee T. Cayton; Gisela A. González-Montiel; M. Ramu Yadav; Douglas L. Orsi; Andrew J. Intelli; Paul Ha-Yeon Cheong; Ryan A. Altman
J. Org. Chem. 2022, 87, 10710–10725
2021
16. Recent developments in decarboxylative C(aryl)–X bond formation from (hetero)aryl carboxylic acids.
Ruchi Sharma, M. Ramu Yadav*
Org. Biomol. Chem. 2021,19, 5476-5500
Post-doctorate Publications
15. Organocatalytic strategy for hydrophenolation of gem-difluoroalkenes
Douglas L.Orsi, M. Ramu Yadav, Ryan A. Altman*
Tetrahedron 2019, 75, 4325-4336.
[Special Symposium in Print in Honor Professor Stephen Buchwald's 2018 Tetrahedron Prize]
14. “Reductive De-nitration of Nitroarenes”
Myuto Kashihara, M. Ramu Yadav, and Yoshiaki Nakao*
Org. Lett. 2018, 20, 1655.
13. “The Buchwald–Hartwig Amination of Nitroarenes”
Fumiyoshi Inoue, Myuto Kashihara, M. Ramu Yadav, and Yoshiaki Nakao*
Angew. Chem. Int. Ed. 2017, 56, 13307.
*Selected as “Hot Paper” by Editors and Highlighted in Angew. Chem. Int. Ed.
12. “The Suzuki–Miyaura Coupling of Nitroarenes”
M. Ramu Yadav†, Masahiro Nagaoka†, Myuto Kashihara, Rong-Lin Zhong, Takanori Miyazaki, Shigeyoshi Sakaki* , and Yoshiaki Nakao*
J. Am. Chem. Soc. 2017,139, 9423 (†Equally Contributed).*Most Accessed Paper 07-2017 to 12-2017*Highlighted in Synfacts, Angew. Chem. Int. Ed. and Featured in Synform
PhD Publications
11. “Ruthenium-Catalyzed ortho-C–H Mono- and Di-imidation of Arenes with N-Tosyloxyphthalimide”
M. Ramu Yadav†, Majji Shankar†, E. Ramesh, Koushik Ghosh, and Akhila K. Sahoo*
Org. Lett. 2015, 17, 1886 (†Equally Contributed).
10. “Sulfoximine Assisted Pd(II)-Catalyzed Bromination and Chlorination of Primary β-C(sp3)–H Bond”
Raja K. Rit, M. Ramu Yadav, Koushik Ghosh, Majji Shankar, and Akhila K. Sahoo*
Org. Lett. 2014, 16, 5258.
9. “Sulfoximine-Directed Ruthenium-Catalyzed ortho-C–H Alkenylation of (Hetero)Arenes: Synthesis of EP3 Receptor Antagonist Analogue”
M. Ramu Yadav, Raja K. Rit, Majji Shankar, and Akhila K. Sahoo*
J. Org. Chem. 2014, 79, 6123.
9. “Sulfoximine-Directed Ruthenium-Catalyzed ortho-C–H Alkenylation of (Hetero)Arenes: Synthesis of EP3 Receptor Antagonist Analogue”
M. Ramu Yadav, Raja K. Rit, Majji Shankar, and Akhila K. Sahoo*
J. Org. Chem. 2014, 79, 6123.
8. “Pd(II)-Catalyzed ortho-C–H Oxidation of Arylacetic Acid Derivatives: Synthesis of Benzofuranones”
Raja K. Rit, M. Ramu Yadav, and Akhila K. Sahoo*
Org. Lett. 2014, 16, 968.
7. “Ru(II)-Catalyzed Intermolecular Ortho-C-H Amidation of Aromatic Ketones with Sulfonyl Azides”
M. Bhanuchandra, M. Ramu Yadav, Raja K. Rit, Malleswara Rao Kuram and Akhila K. Sahoo*
Chem. Commun. 2013, 49, 5225.
6 “Sulfoximine Directed Intermolecular o-C–H Amidation of Arenes with Sulfonyl Azides”
M. Ramu Yadav, Raja K. Rit, and Akhila K. Sahoo*
Org. Lett. 2013, 15, 1638. *Highlighted in Synfacts
5. “Pd(II)-Catalyzed Primary-C(sp3)–H Acyloxylation at Room Temperature”
Raja K. Rit, M. Ramu Yadav, and Akhila K. Sahoo*
Org. Lett. 2012, 14, 3724.
4. “Sulfoximines: A Reusable Directing Group for Chemo- and Regioselective ortho C-H Oxidation of Arenes”
M. Ramu Yadav, Raja K. Rit and Akhila K. Sahoo*
Chem-Eur J. 2012, 18, 5541.
Reviews and Book Chapter
3. “Ruthenium-Catalyzed C-N and C-O Bond Forming Process from C-H Bond Functionalization”
S. Dana, M. Ramu Yadav and Akhila K. Sahoo*
TOMC Springer 2016 “C-H Bond Activation and Catalytic Functionalization I” Vol. 55, pp 189-215 2015 (Invited Book Chapter).
2. “Reusable Directing Groups for sp2 C-H Bond Functionalization of Arenes”
M. Ramu Yadav, Raja K. Rit, Majji Shankar and Akhila K. Sahoo*
Asian J. Org. Chem. 2015, 4, 846 (Invited review).
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1. “Reusable directing groups [8-aminoquinoline, picolinamide, sulfoximine] in C(sp3)–H bond activation: present and future”
Raja K. Rit, M. Ramu Yadav, Koushik Ghosh and Akhila K. Sahoo* Tetrahedron, 2015, 71, 4450 (Invitation in honor of Prof. Yoshiaki Nakao on his being awarded Tetrahedron Young Investigator Award-2015).
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